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Shuangmei Zhou Xiaohan Jia Huimin Yan Xueyuan Peng 《International Journal of Hydrogen Energy》2021,46(42):22122-22133
Low flow rate is one of the primary disadvantages of Roots pumps when they are applied in hydrogen fuel cell vehicles. A novel profile for Roots pumps was developed in this paper to increase the working volume and reduce the internal leakage. The available range of the design parameters of the Roots pump with the new profile was determined analytically, and an improvement in the working volume was validated. The flow dynamics inside the traditional and new pumps were investigated by experiments and numerical simulations. The analytical results indicated that the maximum area utilization of the new profile was approximately 10.4% higher than that of the traditional profile at the same lobe number. The numerical results demonstrated the superiority of the proposed profile in high flow rate and sealing. The tip concentric arcs of the new profile reduced the internal leakage via the radial gap. The characteristic of multipoint meshing within a certain range of rotational angles reduced the interlobe leakage. 相似文献
95.
Vida Janbazi Mahnaz Hashemi 《International Journal of Adaptive Control and Signal Processing》2021,35(2):285-309
This article presents an adaptive neural compensation scheme for a class of large-scale time delay nonlinear systems in the presence of unknown dead zone, external disturbances, and actuator faults. In this article, the quadratic Lyapunov–Krasovskii functionals are introduced to tackle the system delays. The unknown functions of the system are estimated by using radial basis function neural networks. Furthermore, a disturbance observer is developed to approximate the external disturbances. The proposed adaptive neural compensation control method is constructed by utilizing a backstepping technique. The boundedness of all the closed-loop signals is guaranteed via Lyapunov analysis and the tracking errors are proved to converge to a small neighborhood of the origin. Simulation results are provided to illustrate the effectiveness of the proposed control approach. 相似文献
96.
Cátia Azenha Tiago Lagarteira Cecilia Mateos-Pedrero Adélio Mendes 《International Journal of Hydrogen Energy》2021,46(33):17490-17499
Electricity generation for mobile applications by proton exchange membrane fuel cells (PEMFCs) is typically hindered by the low volumetric energy density of hydrogen. Nevertheless, nearly pure hydrogen can be generated in-situ from methanol steam reforming (MSR), with Cu-based catalysts being the most common MSR catalysts. Cu-based catalysts display high catalytic performance, even at low temperatures (ca. 250 °C), but are easily deactivated. On the other hand, Pd-based catalysts are very stable but show poor MSR selectivity, producing high concentrations of CO as by-product. This work studies bimetallic catalysts where Cu was added as a promoter to increase MSR selectivity of Pd. Specifically, the surface composition was tuned by different sequences of Cu and Pd impregnation on a monoclinic ZrO2 support. Both methanol conversion and MSR selectivity were higher for the catalyst with a CuPd-rich surface compared to the catalyst with a Pd-rich surface. Characterization analysis indicate that the higher MSR selectivity results from a strong interaction between the two metals when Pd is impregnated first (likely an alloy). This sequence also resulted in better metallic dispersion on the support, leading to higher methanol conversion. A H2 production rate of 86.3 mmol h?1 g?1 was achieved at low temperature (220 °C) for the best performing catalyst. 相似文献
97.
《International Journal of Hydrogen Energy》2021,46(63):31952-31962
Vanadium redox flow battery (VRFB) is the best choice for large-scale stationary energy storage, but its low energy density affects its overall performance and restricts its development. In order to improve the performance of VRFB, a new type of spiral flow field is proposed, and a multi-physics coupling model and performance metrics evaluation system are established to explore the electrolyte distribution characteristics. The results show that the new spiral flow field can effectively improve the uniformity of electrolyte flow and alleviate the phenomenon of local concentration polarization as compared with the traditional serpentine flow field and parallel flow field. Due to the long flow channel and large pressure drop, the system efficiency is low. However, coulombic efficiency, voltage efficiency and energy efficiency are significantly better than the traditional flow fields. Therefore, the novel flow field has obvious advantages in the application of small stacks. 相似文献
98.
从刨花板生产的刨花筛选与风选相关技术、工艺设计及生产过程工艺控制等方面,阐述了适应刨花分选工艺技术的相关影响因素与技术改进方案。 相似文献
99.
为提高设计效率并快速得到适于工程应用的高压压气机转子结构,以改型设计方法为基础对某高压压气机转子结构进行了详细设计,同时对结构改进方法进行了一定的探索。采用叶—盘耦合系统循环对称结构算法及整体转子系统二维轴对称结构算法进行强度设计及改进,前轴颈最大应力下降最多达26%;其次进行支承结构设计,计算校核母型机轴承承载能力。结果表明:轴向力安全裕度最小为28%,轴承寿命大于100 000 h;给出2种调整鼠笼厚度的估算方法用以指导三维有限元计算,同时计算得到前支承刚度;通过二维有限元分析模型计算转子的临界转速,仅将后轴承支承位置沿压气机轴线向后移动7.5 mm,全运行工况转速与第2阶临界转速的安全裕度由18.5%提高到21.2%。 相似文献
100.
Guangbo Zeng Dongqing Zhang Liuming Yan Baohua Yue Ting Pan Yidong Hu Shufa He Hongbin Zhao Jiujun Zhang 《International Journal of Hydrogen Energy》2021,46(39):20664-20677
Side-chain optimized poly (2,6-dimethyl-1,4-phenylene oxide)-g-poly (styrene sulfonic acid) (PPO-g-PSSA) is designed with balanced water-resistance and sulfonation degree. The PPO-g-PSSA is synthesized by controlled atom-transfer radical polymerization (ATRP) from brominated poly (2,6-dimethyl-1,4-phenylene oxide) (PPO-xBr) and ethyl styrene-4-sulfonate and followed by hydrolysis. A series of PPO-g-PSSA are prepared possessing different bromination degree (x) of PPO-xBr and polymerization degree (m) of the side-chains and the water-resistances of the fabricated membranes are investigated. The results show that a PPO-g-PSSA at relatively low x (x < 0.2) and high m (m > 4) exhibits good balance between the water-resistance and the sulfonation degree. Namely, it displays suitable proton conductivity with compromised water-resistance. Moreover, a maximum ion exchange capacity (IEC) of 3.24 mmol g?1 is reached without the sacrifice of water-resistance. In addition, PPO-g-0.08PSSA-13 and PPO-g-0.14PSSA-4 are chosen characterized by thermogravimetric analysis, proton conductivities and mechanical properties. At 90% RH, the optimized PPO-g-0.08PPSA-13 possesses a proton conductivity of 37.9 mS cm?1 at 40 °C and 45.5 mS cm?1 at 95 °C, respectively. 相似文献